Department of Chemistry and Physics |
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CHEM2004 |
Exam 3
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CHEM2004 Name_______________________
Exam 3 Fall 2006
1. Show a) the reaction of perchloric acid in water and b) the reaction of nitric acid in water. How do these reactions explain the leveling effect? (10 points)
a)
b)
2. Describe the effect on pH of each of the following when placed in water: (6 points)
a) Na2O -
b) SO3 -
c) RuO4 -
3. Fill in the blank with the appropriate oxide or oxoacid. (1 point each)
Syn-gas ________________________________________
Photosynthesis __________________________________
Used as fire extinguisher ___________________________
Number one chemical produced in tons per year _________________________
Oxide used as a drying agent _________________________________
Oxoacid used to make ammonium nitrate __________________________
Oxide used to make phosphoric acid _________________________________
Used to make carbonated beverages ___________________________
4. Predict the product(s) for the following reaction: Label the acidic oxide, the basic oxide and balance the equation. (12 points)
CO2 + MoO3 g
P2O5 + CoO g
Cr2O3 + H2O g
BaO + CO2 g
5. Determine the C.N.(+), C.N.(-), the lattice and expected properties for: (12 points)
|
lattice |
C.N.(+) |
C.N.(-) |
properties
|
Mn2O3 |
|
|
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KF |
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Cu2O |
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|
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Mn 78; F 119; O 126; Cu 91; K 152 pm
6. Describe the role of CO2 in the Greenhouse effect. (4 points)
7. Why should you be careful when using P4O10 as a drying agent for organic solvents? (4 points)
8. List the environmental problems associated with NOx’s. (9 points)
9. Describe how phosphoric acid is prepared from elemental phosphorus. (6 points)
10. Describe how sulfuric acid is prepared starting from sulfide ores. (6 points)
11. Why do oxides of metals at the right of the period generally have lower melting points than those to the left of the period? (6 points)
12. Why is it difficult to make pure strong oxoacids? (4 points)
13. List three common uses for sulfuric acid . (6 points)
14. How is forsterite made? What is it used for? (7 points)
r+/ r- |
Lattice type |
C.N. (+) |
C.N. (-) |
a) MX |
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|
|
0.225 – 0.414 |
Wurtzite |
4 |
4 |
|
Zinc blende |
4 |
4 |
0.414 – 0.732 |
Rock salt |
6 |
6 |
0.732 – 1.000 |
CsCl |
8 |
8 |
b) MX2 |
|
|
|
0.225 – 0.414 |
Beta-quartz |
4 |
2 |
0.414 – 0.732 |
Rutile |
6 |
3 |
0.732 – 1.000 |
Fluorite |
8 |
4 |
c) M2X3 |
|
|
|
0.414 – 0.732 |
corundum |
6 |
4 |
d) other |
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|
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Never favored |
Ion pair |
1 |
1 |
0.000 – 0.155 |
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2 |
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0.155 – 0.225 |
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3 |
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0.225 – 0.414 |
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4 |
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0.414 – 0.732 |
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6 |
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0.732 – 1.000 |
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8 |
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1.000 |
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12 |
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