Department of Chemistry and Physics |
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CHEM2004 |
Exam 5
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CHEM2004 Name_______________________
Exam 5 Fall 2009
1. Balance the following redox equation: SHOW WORK (10 points)
Mn+2 (aq) + BiO3 - (aq) g Bi+3 (aq) + MnO4 - (aq) (acidic solution)
2. Write the Nernst equation for the balanced reaction in problem 1: Is the cell potential pH dependent? (6 points)
3. List the 5 potentially hazardous combinations and give an example for each. (15 points)
4. List two very electronegative nonmetals. (4 points)
5. In class, the activity of the metals were categorized by their electronegativities. Give the three classes. (3 points)
6. Match the class of silicate with each of the following substances. (1 point each – 15 points total)
_____ micas |
A. simple silicate |
_____ amphibole |
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_____ asbestos |
B. linear silicate |
_____ pyroxene | |
_____ biotite |
C. cyclic silicate |
_____ garnet |
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_____ tremolite |
D. chain silicate |
_____ vermiculite | |
_____ montmorillonite | E. polymeric sheet silicate |
_____ agate | |
_____ quartz | F. three dimensional silicate |
_____ beryl | |
_____ thortveitite | |
_____ onyx | |
_____ metasilicates |
7. Describe how glass is made. Use the terms acidic oxide and basic oxide in your answer. (8 points)
8. Draw the structure of a pyroxene showing four units. (3 points)
9. Match the oxide or oxoanion that best fits or describes each of the following: (1 point each)
_____ biological stain | a) B2O3 |
_____ Portland cement | b) Na2B4O7 |
_____ Borax | c) ClO2 |
_____ color TV tubes | d) [AlxSiyO2x+2y]x- |
_____ used as bleach | e) Al6O1818- |
_____ Heteropoly Blues | f) Na5P3O10 |
_____ pyrex | g) [X+nM12O40](8-n)- |
_____ fine crystal | h) SrO |
_____ zeolites | i) V10O286- |
_____ polyvanadate | k) PbO |
m) La2O3 | |
o) Mo7O246- | |
p) OsO4 | |
10. For each of the following pairs, circle the compound that is easiest to reduce. (2 points each)
a) NO3- or H3PO4
b) GeO2 or Ga+3
c) MnO4- or ReO4-
11. Fill in the blank. (2 points each)
a) Name of the effect that causes current to flow when a pressure is applied
_________________________________
b) For a spontaneous process the sign of Eo is ___________________
c) High melting solids with a low volatility _______________________________
d) Process of mixing powders and heating to high temperatures, allowing the powders to slowly fuse into each others’ lattices ____________________________
e) Solids without a regular crystalline pattern are said to be ________________________
f) Problem in the lattice when atoms are
missing from the structure is called a
_________________________________
g) Oxides that do not have a whole number ratio of metal to oxygen are _____________________________________________
h) Oxides that are not formed from acidic oxides and do not have identifiable oxo anions (ex. BaTiO3) __________________________________
12. State the First Principle of Isomorphous Substitution and give an example. (6 points)