Arkansas State University  Department of Chemistry and Physics
CHEM2004	Exam 8

CHEM2004                                                                 Final Exam 2009

Place answers on the answer sheet.  Good Luck.

1.         The number of bonds expected for S is

a)  1                 b)  2                 c)  3                 d)  4

2.         Which element has the highest enthalpy of atomization?

a)  Sb              b)  P                c)  N                d)  F

3.         Which is not an allotrope of oxygen?

a)  atomic oxygen                             b)  molecular oxygen

c)  ozonide                       d)  ozone

4.         Which element would have the largest band gap? 

a)  O                b)  S                c)  Cl               d)  Au

5.         Mineral used as molecular sieves for drying solvents

a)  Fluorapatite          b)  Augite                   c)  Zeolite       d)  Tremolite

6.         The smallest radius for an element is

a)  covalent                b)  anionic                  c) cationic      d) van der Waal

7.         Which ion is not precipitated with carbonate in the qual scheme?

a) Ca⁺²                        b) Cu⁺²            c) Ba⁺²                        d) Mg⁺²

8.         Classify the basicity of SiO₄^4- 

a)  nonbasic                      b)  feebly basic

c)  moderately basic                         d)  very strongly basic

9.         The hydration energy depends on three factors, which is not one of these three?

a)  charge                                           b)  electronegativity

c)  radius                                            d)  water polarity

10.       The oxoanion for Mo⁺⁶

a)  MoO₄^-        b) MoO₄^-2       c)  MoO₅^-3         d) MoO₆^-5 

11.       Cations which undergo a small amount of hydrolysis with water are classified as

a) nonacidic                      b) feebly acidic

c) moderately acidic                         d) very strongly acidic

12.       Which is the strongest acid?

a)  HClO₄                    b)  HClO₃                    c)  H₂SO₃                    d)  HNO₂

13.       Pyrex is made by adding what to the glass mixture?

a)  B₂O₃                      b)  PbO                       c)  SrO                        d)  La₂O₃

14.       Olivine is an example of

a)  cyclic polysilicate              b)  chain polysilicate

c)  linear silicates                              d)  simple silicates

15.       Asbestos are

a)  pyroxenes             b)  amphiboles          c)  zeolites                 d)  metasilicates

16.       What color is Ni⁺² solution?

a)  blue           b)  green         c)  red             d)  yellow

17.       For the half-reaction:  IO ^-   g  I₂, the number of electrons transferred is

a)  1                 b)  2                 c)  3                 d)  4

18.       The product for the Wilkinson process is

a)  acetic acid                        b)  olefin polymers

c) acetaldehyde                    d)  hydrogenated olefins

19.       Color of the Ba flame test

a)  blue           b)  green         c)  red             d)  yellow

20.       The reaction of CO with H₂ to produce hydrocarbons and water is called

a)  Fischer-Tropsch process                       b)  Water gas shift reaction

c)  Monsanto process                                  d)  Wacker process

21.       Protein used for carrying ferrous ions across bacterial cell walls

a)  myoglobin                     b)  hemoglobin

c)  metallothionein                d)  siderophore

22.       Which ion is not a Group V ion?

a)  Ca⁺²           b)  Ba⁺²           c)  Mg⁺²          d)  V⁺³

23.       Which is not a type of sulfur found in coal?

a)  pyritic        b) sulfatic       c)  carbonated           d)  organic

 24.       The metal found in the blood of scorpions

a)  Fe               b)  Cu              c)  Co              d)  Cr

25.       A prepared for bonding configuration of s¹p_x¹p_y¹p_z¹ represents

a)  Mg             b)  Al               c)  Si               d) P

26.       Which is not a good ligand?

a)  fluoride                             b)  bromide

c)  water                                 d)  hydroxide 

27.       CeO₂ is an example of a(n)

a)  nonstoichiometric oxide             b) spinel        

c)  refractory                                      d) amphibole

28.       For the compound M₃X₄, if the C.N. for M is 4, the C.N. for X is

a)  2                 b)  3                 c) 4                  d)  12

29.       The oxoanion of this element is found in detergent

a)  Al               b)  Pb              c)  Ce              d)  B

30.       M(OH₂)₄(OH)₂²⁺ is an example of a(n)

a) oxoanion    b) oxoacid      c) hydroxycation       d) hydroxyanion

31.       The number of valence electrons in Cu⁺²

a) 0                  b)  2                 c)  7                 d)  9

32.       Cadmium poisoning is associated with

a)  itai itai                 b)  Mad Hatter’s disease

c)  Alzheimer’s                      d)  arthritis

33.       Which element shows the least metallic character?

a)  Li                b)  Fr               c)  Rb              d)  K

34.       Element most likely to form catenates

a)  N                b)  O                c)  P                d)  S   

35.       For precipitation reactions, DG is

a)  positive     b)  negative    c) zero                        d) not important

 36.       Which ion below would have a colored solution?

a)  Fe⁺³            b)  Zn⁺²           c)  Cl^-              d)  Ti⁺⁴

37.       Most common oxidation state for lanthanides

a)  + 2              b)  + 3             c)  + 4              d) + 5

38.       The reaction of CaO with SO₃ gives

a)  SCaO₄       b) CaSO₄        c)  Ca₂SO₅      d)  Ca₃SO₆

39.       Number one chemical produced in terms of tons/year

a)  sulfuric acid                     b)  hydrochloric acid

c)  nitric acid                          d)  phosphoric acid

40.       Which compound is not a hazardous electrochemical combination?

a)  NaCl

b)  TNT

c)  NaN₃

d)  NH₄NO₃

41.       Most metals precipitate with the addition of sulfide ion.  Which metal does not give a black precipitate?

a)  Co              b) Ni                c) Cd               d) Hg

42.       Volatile oxide used as a refrigerant and as a fire extinguisher

a)  CO             b)  CO₂           c)  H₂CO₃       d)  Na₂CO₃

43.       Which element is associated with blood clotting?

a)  Ca              b)  Al               c)  Fe               d)  Pb

44.       The maximum (+) oxidation state for S is

a)  +2               b)  +4              c)  +6               d)  +8

45.       Which Noble gas is most abundant?

a)  Ar               b)  Kr              c)  Rn              d)  He

46.       Which atom has the lowest polarizability?

a)  O                b)  F                c)  I                  d)  Cl

47.       Allotrope of phosphorous that exists as tetrahedrals

a)  white         b)  red             c)  black          d)  yellow

48.       Transition metal found in sea squirts

a)  Co              b) Mo              c) Cr                d) V

49.       Which is a physical property of nonmetals?

a)  good conductors                         b)  ductile

c)  malleable                                    d)  transparent as thin sheets

50.       Which Noble gas has the highest melting point?

a)  H₂               b) F₂                c) Br₂              d) I₂